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| [[Category:Compressible flow]] | | [[Category:Compressible flow]] |
| [[Category:Thermodynamics]] | | [[Category:Thermodynamics]]<!-- |
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| | -->{{#vardefine:secno|1}}<!-- |
| | -->{{#vardefine:eqno|23}}<!-- |
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| | {{NumEqn|<math> |
| | ds=C_v\dfrac{dT}{T}+R\dfrac{d\nu}{\nu} |
| | </math>|label=eq_process_ds_a}} |
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|
| \section{Thermodynamics}
| | {{NumEqn|<math> |
| | |
| \subsection{Specific Heat Relations}
| |
| | |
| \noindent For thermally perfect and calorically perfect gases\\
| |
| | |
| \begin{equation}
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| \begin{aligned}
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| &C_p=\frac{dh}{dT}\\
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| &C_v=\frac{de}{dT}
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| \end{aligned}
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| \label{eq:specificheat}
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| \end{equation}\\
| |
| | |
| \noindent From the definition of enthalpy and the equation of state $p=\rho RT$\\
| |
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| \begin{equation}
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| h=e+\frac{p}{\rho}=e+RT
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| \label{eq:enthalpy}
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| \end{equation}\\
| |
| | |
| \noindent Differentiate Eqn. \ref{eq:enthalpy} with respect to temperature gives\\
| |
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| \begin{equation}
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| \frac{dh}{dT}=\frac{de}{dT}+\frac{d(RT)}{dT}
| |
| \label{eq:enthalpy:b}
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| \end{equation}\\
| |
| | |
| \noindent Inserting the specific heats gives\\
| |
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| \begin{equation}
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| C_p=C_v+R
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| \label{eq:specificheat:b}
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| \end{equation}\\
| |
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| \noindent Dividing Eqn. \ref{eq:specificheat:b} by $C_v$ gives\\
| |
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| \begin{equation}
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| \frac{C_p}{C_v}=1+\frac{R}{C_v}
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| \label{eq:specificheat:c}
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| \end{equation}\\
| |
| | |
| \noindent Introducing the ratio of specific heats defined as\\
| |
| | |
| \begin{equation}
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| \gamma=\frac{C_p}{C_v}
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| \label{eq:gamma}
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| \end{equation}\\
| |
| | |
| \noindent Now, inserting Eqn. \ref{eq:gamma} in Eqn. \ref{eq:specificheat:c} gives\\
| |
| | |
| \begin{equation}
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| C_v=\frac{R}{\gamma-1}
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| \label{eq:specificheat:d}
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| \end{equation}\\
| |
| | |
| \noindent In the same way, dividing Eqn. \ref{eq:specificheat:b} with $C_p$ gives\\
| |
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| \begin{equation}
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| 1=\frac{C_v}{C_p}+\frac{R}{C_p}=\frac{1}{\gamma}+\frac{R}{C_p}
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| \label{eq:specificheat:e}
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| \end{equation}\\
| |
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| \noindent and thus\\
| |
| | |
| \begin{equation}
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| C_p=\frac{\gamma R}{\gamma-1}
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| \label{eq:specificheat:f}
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| \end{equation}\\
| |
| | |
| \subsection{Isentropic Relations}
| |
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| First law of thermodynamics:\\
| |
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| \begin{equation}
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| de=\delta q - \delta w
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| \label{eq:firstlaw}
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| \end{equation}\\
| |
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| \noindent For a reversible process: $\delta w=pd(1/\rho)$ and $\delta q=Tds$\\
| |
| | |
| \begin{equation}
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| de=Tds-pd\left(\frac{1}{\rho}\right)
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| \label{eq:firstlaw:b}
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| \end{equation}\\
| |
| | |
| \noindent Enthalpy is defined as: $h=e+p/\rho$ and thus\\
| |
| | |
| \begin{equation}
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| dh=de+pd\left(\frac{1}{\rho}\right)+\left(\frac{1}{\rho}\right)dp
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| \label{eq:dh}
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| \end{equation}\\
| |
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| \noindent Eliminate $de$ in Eqn. \ref{eq:firstlaw:b} using Eqn. \ref{eq:dh}\\
| |
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| \[Tds=dh-\cancel{pd\left(\frac{1}{\rho}\right)}-\left(\frac{1}{\rho}\right)dp+\cancel{pd\left(\frac{1}{\rho}\right)}\]\\
| |
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| \[ds=\frac{dh}{T}-\frac{dp}{\rho T}\]\\
| |
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| \noindent Using $dh=C_p T$ and the equation of state $p=\rho RT$, we get\\
| |
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| \begin{equation}
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| ds=C_p\frac{dT}{T}-R\frac{dp}{p}
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| \label{eq:ds}
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| \end{equation}\\
| |
| | |
| \noindent Integrating Eqn. \ref{eq:ds} gives\\
| |
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| \begin{equation}
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| s_2-s_1=\int_1^2 C_p\frac{dT}{T}-R\ln\left(\frac{p_2}{p_1}\right)
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| \label{eq:ds:b}
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| \end{equation}\\
| |
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| \noindent For a calorically perfect gas, $C_p$ is constant (not a function of temperature) and can be moved out from the integral and thus\\
| |
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| \begin{equation}
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| s_2-s_1=C_p\ln\left(\frac{T_2}{T_1}\right)-R\ln\left(\frac{p_2}{p_1}\right)
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| \label{eq:ds:c}
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| \end{equation}\\
| |
| | |
| \noindent An alternative form of Eqn. \ref{eq:ds:c} is obtained by using $de=C_v dT$ Eqn. \ref{eq:firstlaw:b}, which gives\\
| |
| | |
| \begin{equation}
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| s_2-s_1=\int_1^2 C_v\frac{dT}{T}-R\ln\left(\frac{\rho_2}{\rho_1}\right)
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| \label{eq:ds:d}
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| \end{equation}\\
| |
| | |
| \noindent Again, for a calorically perfect gas, we get\\
| |
| | |
| \begin{equation}
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| s_2-s_1=C_v\ln\left(\frac{T_2}{T_1}\right)-R\ln\left(\frac{\rho_2}{\rho_1}\right)
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| \label{eq:ds:e}
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| \end{equation}\\
| |
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| \section*{Isentropic Relations}
| |
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| \noindent Adiabatic and reversible processes, i.e., isentropic processes implies $ds=0$ and thus Eqn. \ref{eq:ds:c} reduces to\\
| |
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| \[\frac{C_p}{R}\ln\left(\frac{T_2}{T_1}\right)=\ln\left(\frac{p_2}{p_1}\right)\]\\
| |
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| \[\frac{C_p}{R}=\frac{\gamma}{\gamma-1}\]\\
| |
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| \[\frac{\gamma}{\gamma-1}\ln\left(\frac{T_2}{T_1}\right)=\ln\left(\frac{p_2}{p_1}\right)\Rightarrow\]\\
| |
| | |
| \begin{equation}
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| \frac{p_2}{p_1}=\left(\frac{T_2}{T_1}\right)^{\gamma/(\gamma-1)}
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| \label{eq:isentropic:a}
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| \end{equation}\\
| |
| | |
| \noindent In the same way, Eqn. \ref{eq:ds:e} gives\\
| |
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| \begin{equation}
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| \frac{\rho_2}{\rho_1}=\left(\frac{T_2}{T_1}\right)^{1/(\gamma-1)}
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| \label{eq:isentropic:b}
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| \end{equation}\\
| |
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| \noindent Eqn. \ref{eq:isentropic:a} and Eqn. \ref{eq:isentropic:b} constitutes the isentropic relations\\
| |
| | |
| \begin{equation}
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| \frac{p_2}{p_1}=\left(\frac{\rho_2}{\rho_1}\right)^{\gamma}=\left(\frac{T_2}{T_1}\right)^{\gamma/(\gamma-1)}
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| \label{eq:isentropic:a}
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| \end{equation}
| |
| | |
| \section{Flow Processes}
| |
| | |
| \[ds=C_v\dfrac{dT}{T}+R\dfrac{d\nu}{\nu}\]
| |
| | |
| \begin{equation}
| |
| d\nu=\dfrac{\nu}{R}ds-C_v\dfrac{\nu}{RT}dT=\dfrac{\nu}{R}ds-\dfrac{C_v}{p}dT | | d\nu=\dfrac{\nu}{R}ds-C_v\dfrac{\nu}{RT}dT=\dfrac{\nu}{R}ds-\dfrac{C_v}{p}dT |
| \label{eqn:process:dnu}
| | </math>|label=eq_process_dnu}} |
| \end{equation}
| |
|
| |
|
| \noindent for an isentropic process ($ds=0$), $d\nu < 0$ for positive values of $dT$.
| | for an isentropic process (<math>ds=0</math>), <math>d\nu < 0</math> for positive values of <math>dT</math>. |
|
| |
|
| \[ds=C_p\dfrac{dT}{T} - R \dfrac{dp}{p}\]
| | {{NumEqn|<math> |
| | ds=C_p\dfrac{dT}{T} - R \dfrac{dp}{p} |
| | </math>|label=eq_process_ds_b}} |
|
| |
|
| \[dp=-\dfrac{p}{R}ds+C_p\dfrac{p}{RT}dT=-\dfrac{p}{R}ds+C_p\rho dT\]
| | {{NumEqn|<math> |
| | dp=-\dfrac{p}{R}ds+C_p\dfrac{p}{RT}dT=-\dfrac{p}{R}ds+C_p\rho dT |
| | </math>|label=eq_process_dp}} |
|
| |
|
| \noindent for an isentropic process ($ds=0$), $dp > 0$ for positive values of $dT$.
| | for an isentropic process (<math>ds=0</math>), <math>dp > 0</math> for positive values of <math>dT</math>. |
|
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| \noindent Since $\nu$ decreases with temperature and pressure increases with temperature for an isentropic process, we can see from Eqn.~\ref{eqn:process:dnu} that $d\nu$ will be greater at lower temperatures and thus isochores (lines of constant specific volume) will be closely spaced at low temperatures and more sparse at higher temperatures. For an isochore $dv=0$ which implies
| | Since <math>\nu</math> decreases with temperature and pressure increases with temperature for an isentropic process, we can see from {{EquationNote|label=eq_process_dnu}} that <math>d\nu</math> will be greater at lower temperatures and thus isochores (lines of constant specific volume) will be closely spaced at low temperatures and more sparse at higher temperatures. For an isochore <math>dv=0</math> which implies |
|
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|
| \[0=\dfrac{\nu}{R}\left(ds-C_v\dfrac{dT}{T}\right) \Rightarrow \dfrac{dT}{ds}=\dfrac{T}{C_v}\]
| | {{NumEqn|<math> |
| | 0=\dfrac{\nu}{R}\left(ds-C_v\dfrac{dT}{T}\right) \Rightarrow \dfrac{dT}{ds}=\dfrac{T}{C_v} |
| | </math>}} |
|
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|
| \noindent and thus we can see that the slope of an isochore in a $T-s$-diagram is positive and that the slope increases with temperature.
| | and thus we can see that the slope of an isochore in a <math>T-s</math>-diagram is positive and that the slope increases with temperature. |
|
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|
| \noindent In analogy, we can see that an isobar ($dp=0$) leads to the following relation
| | In analogy, we can see that an isobar (<math>dp=0</math>) leads to the following relation |
|
| |
|
| \[0=\dfrac{p}{R}\left(C_p\dfrac{dT}{T}-ds\right) \Rightarrow \dfrac{dT}{ds}=\dfrac{T}{C_p}\]
| | {{NumEqn|<math> |
| | 0=\dfrac{p}{R}\left(C_p\dfrac{dT}{T}-ds\right) \Rightarrow \dfrac{dT}{ds}=\dfrac{T}{C_p} |
| | </math>}} |
|
| |
|
| \noindent and consequently isobars will also have a positive slope that increases with temperature in a $T-s$-diagram. Moreover, isobars are less steep than ischores as $C_p > C_v$.
| | and consequently isobars will also have a positive slope that increases with temperature in a <math>T-s</math>-diagram. Moreover, isobars are less steep than ischores as <math>C_p > C_v</math>. |
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