Thermodynamic processes: Difference between revisions

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Created page with "Category:Compressible flow Category:Thermodynamics __TOC__ \section{Thermodynamics} \subsection{Specific Heat Relations} \noindent For thermally perfect and calorically perfect gases\\ \begin{equation} \begin{aligned} &C_p=\frac{dh}{dT}\\ &C_v=\frac{de}{dT} \end{aligned} \label{eq:specificheat} \end{equation}\\ \noindent From the definition of enthalpy and the equation of state $p=\rho RT$\\ \begin{equation} h=e+\frac{p}{\rho}=e+RT \label{eq:enthalpy} \end..."
 
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{{NumEqn|<math>
ds=C_v\dfrac{dT}{T}+R\dfrac{d\nu}{\nu}
</math>|label=eq_process_ds_a}}


\section{Thermodynamics}
{{NumEqn|<math>
 
\subsection{Specific Heat Relations}
 
\noindent For thermally perfect and calorically perfect gases\\
 
\begin{equation}
\begin{aligned}
&C_p=\frac{dh}{dT}\\
&C_v=\frac{de}{dT}
\end{aligned}
\label{eq:specificheat}
\end{equation}\\
 
\noindent From the definition of enthalpy and the equation of state $p=\rho RT$\\
 
\begin{equation}
h=e+\frac{p}{\rho}=e+RT
\label{eq:enthalpy}
\end{equation}\\
 
\noindent Differentiate Eqn. \ref{eq:enthalpy} with respect to temperature gives\\
 
\begin{equation}
\frac{dh}{dT}=\frac{de}{dT}+\frac{d(RT)}{dT}
\label{eq:enthalpy:b}
\end{equation}\\
 
\noindent Inserting the specific heats gives\\
 
\begin{equation}
C_p=C_v+R
\label{eq:specificheat:b}
\end{equation}\\
 
\noindent Dividing Eqn. \ref{eq:specificheat:b} by $C_v$ gives\\
 
\begin{equation}
\frac{C_p}{C_v}=1+\frac{R}{C_v}
\label{eq:specificheat:c}
\end{equation}\\
 
\noindent Introducing the ratio of specific heats defined as\\
 
\begin{equation}
\gamma=\frac{C_p}{C_v}
\label{eq:gamma}
\end{equation}\\
 
\noindent Now, inserting Eqn. \ref{eq:gamma} in Eqn. \ref{eq:specificheat:c} gives\\
 
\begin{equation}
C_v=\frac{R}{\gamma-1}
\label{eq:specificheat:d}
\end{equation}\\
 
\noindent In the same way, dividing Eqn. \ref{eq:specificheat:b} with $C_p$ gives\\
 
\begin{equation}
1=\frac{C_v}{C_p}+\frac{R}{C_p}=\frac{1}{\gamma}+\frac{R}{C_p}
\label{eq:specificheat:e}
\end{equation}\\
 
\noindent and thus\\
 
\begin{equation}
C_p=\frac{\gamma R}{\gamma-1}
\label{eq:specificheat:f}
\end{equation}\\
 
\subsection{Isentropic Relations}
 
First law of thermodynamics:\\
 
\begin{equation}
de=\delta q - \delta w
\label{eq:firstlaw}
\end{equation}\\
 
\noindent For a reversible process: $\delta w=pd(1/\rho)$ and $\delta q=Tds$\\
 
\begin{equation}
de=Tds-pd\left(\frac{1}{\rho}\right)
\label{eq:firstlaw:b}
\end{equation}\\
 
\noindent Enthalpy is defined as: $h=e+p/\rho$ and thus\\
 
\begin{equation}
dh=de+pd\left(\frac{1}{\rho}\right)+\left(\frac{1}{\rho}\right)dp
\label{eq:dh}
\end{equation}\\
 
\noindent Eliminate $de$ in Eqn. \ref{eq:firstlaw:b} using Eqn. \ref{eq:dh}\\
 
\[Tds=dh-\cancel{pd\left(\frac{1}{\rho}\right)}-\left(\frac{1}{\rho}\right)dp+\cancel{pd\left(\frac{1}{\rho}\right)}\]\\
 
\[ds=\frac{dh}{T}-\frac{dp}{\rho T}\]\\
 
\noindent Using $dh=C_p T$ and the equation of state $p=\rho RT$, we get\\
 
\begin{equation}
ds=C_p\frac{dT}{T}-R\frac{dp}{p}
\label{eq:ds}
\end{equation}\\
 
\noindent Integrating Eqn. \ref{eq:ds} gives\\
 
\begin{equation}
s_2-s_1=\int_1^2 C_p\frac{dT}{T}-R\ln\left(\frac{p_2}{p_1}\right)
\label{eq:ds:b}
\end{equation}\\
 
\noindent For a calorically perfect gas, $C_p$ is constant (not a function of temperature) and can be moved out from the integral and thus\\
 
\begin{equation}
s_2-s_1=C_p\ln\left(\frac{T_2}{T_1}\right)-R\ln\left(\frac{p_2}{p_1}\right)
\label{eq:ds:c}
\end{equation}\\
 
\noindent An alternative form of Eqn. \ref{eq:ds:c} is obtained by using $de=C_v dT$ Eqn. \ref{eq:firstlaw:b}, which gives\\
 
\begin{equation}
s_2-s_1=\int_1^2 C_v\frac{dT}{T}-R\ln\left(\frac{\rho_2}{\rho_1}\right)
\label{eq:ds:d}
\end{equation}\\
 
\noindent Again, for a calorically perfect gas, we get\\
 
\begin{equation}
s_2-s_1=C_v\ln\left(\frac{T_2}{T_1}\right)-R\ln\left(\frac{\rho_2}{\rho_1}\right)
\label{eq:ds:e}
\end{equation}\\
 
\section*{Isentropic Relations}
 
\noindent Adiabatic and reversible processes, i.e., isentropic processes implies $ds=0$ and thus Eqn. \ref{eq:ds:c} reduces to\\
 
\[\frac{C_p}{R}\ln\left(\frac{T_2}{T_1}\right)=\ln\left(\frac{p_2}{p_1}\right)\]\\
 
\[\frac{C_p}{R}=\frac{\gamma}{\gamma-1}\]\\
 
\[\frac{\gamma}{\gamma-1}\ln\left(\frac{T_2}{T_1}\right)=\ln\left(\frac{p_2}{p_1}\right)\Rightarrow\]\\
 
\begin{equation}
\frac{p_2}{p_1}=\left(\frac{T_2}{T_1}\right)^{\gamma/(\gamma-1)}
\label{eq:isentropic:a}
\end{equation}\\
 
\noindent In the same way, Eqn. \ref{eq:ds:e} gives\\
 
\begin{equation}
\frac{\rho_2}{\rho_1}=\left(\frac{T_2}{T_1}\right)^{1/(\gamma-1)}
\label{eq:isentropic:b}
\end{equation}\\
 
\noindent Eqn. \ref{eq:isentropic:a} and Eqn. \ref{eq:isentropic:b} constitutes the isentropic relations\\
 
\begin{equation}
\frac{p_2}{p_1}=\left(\frac{\rho_2}{\rho_1}\right)^{\gamma}=\left(\frac{T_2}{T_1}\right)^{\gamma/(\gamma-1)}
\label{eq:isentropic:a}
\end{equation}
 
\section{Flow Processes}
 
\[ds=C_v\dfrac{dT}{T}+R\dfrac{d\nu}{\nu}\]
 
\begin{equation}
d\nu=\dfrac{\nu}{R}ds-C_v\dfrac{\nu}{RT}dT=\dfrac{\nu}{R}ds-\dfrac{C_v}{p}dT
d\nu=\dfrac{\nu}{R}ds-C_v\dfrac{\nu}{RT}dT=\dfrac{\nu}{R}ds-\dfrac{C_v}{p}dT
\label{eqn:process:dnu}
</math>|label=eq_process_dnu}}
\end{equation}


\noindent for an isentropic process ($ds=0$), $d\nu < 0$ for positive values of $dT$.
for an isentropic process (<math>ds=0</math>), <math>d\nu < 0</math> for positive values of <math>dT</math>.


\[ds=C_p\dfrac{dT}{T} - R \dfrac{dp}{p}\]
{{NumEqn|<math>
ds=C_p\dfrac{dT}{T} - R \dfrac{dp}{p}
</math>|label=eq_process_ds_b}}


\[dp=-\dfrac{p}{R}ds+C_p\dfrac{p}{RT}dT=-\dfrac{p}{R}ds+C_p\rho dT\]
{{NumEqn|<math>
dp=-\dfrac{p}{R}ds+C_p\dfrac{p}{RT}dT=-\dfrac{p}{R}ds+C_p\rho dT
</math>|label=eq_process_dp}}


\noindent for an isentropic process ($ds=0$), $dp > 0$ for positive values of $dT$.
for an isentropic process (<math>ds=0</math>), <math>dp > 0</math> for positive values of <math>dT</math>.


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\noindent Since $\nu$ decreases with temperature and pressure increases with temperature for an isentropic process, we can see from Eqn.~\ref{eqn:process:dnu} that $d\nu$ will be greater at lower temperatures and thus isochores (lines of constant specific volume) will be closely spaced at low temperatures and more sparse at higher temperatures. For an isochore $dv=0$ which implies
Since <math>\nu</math> decreases with temperature and pressure increases with temperature for an isentropic process, we can see from {{EquationNote|label=eq_process_dnu}} that <math>d\nu</math> will be greater at lower temperatures and thus isochores (lines of constant specific volume) will be closely spaced at low temperatures and more sparse at higher temperatures. For an isochore <math>dv=0</math> which implies


\[0=\dfrac{\nu}{R}\left(ds-C_v\dfrac{dT}{T}\right) \Rightarrow \dfrac{dT}{ds}=\dfrac{T}{C_v}\]
{{NumEqn|<math>
0=\dfrac{\nu}{R}\left(ds-C_v\dfrac{dT}{T}\right) \Rightarrow \dfrac{dT}{ds}=\dfrac{T}{C_v}
</math>}}


\noindent and thus we can see that the slope of an isochore in a $T-s$-diagram is positive and that the slope increases with temperature.
and thus we can see that the slope of an isochore in a <math>T-s</math>-diagram is positive and that the slope increases with temperature.


\noindent In analogy, we can see that an isobar ($dp=0$) leads to the following relation
In analogy, we can see that an isobar (<math>dp=0</math>) leads to the following relation


\[0=\dfrac{p}{R}\left(C_p\dfrac{dT}{T}-ds\right) \Rightarrow \dfrac{dT}{ds}=\dfrac{T}{C_p}\]
{{NumEqn|<math>
0=\dfrac{p}{R}\left(C_p\dfrac{dT}{T}-ds\right) \Rightarrow \dfrac{dT}{ds}=\dfrac{T}{C_p}
</math>}}


\noindent and consequently isobars will also have a positive slope that increases with temperature in a $T-s$-diagram. Moreover, isobars are less steep than ischores as $C_p > C_v$.  
and consequently isobars will also have a positive slope that increases with temperature in a <math>T-s</math>-diagram. Moreover, isobars are less steep than ischores as <math>C_p > C_v</math>.  


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