Isentropic relations: Difference between revisions

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First law of thermodynamics:
First law of thermodynamics:


{{NumEqn|<math>de=\delta q - \delta w</math>|1}}
{{NumEqn|<math>de=\delta q - \delta w</math>}}


For a reversible process: <math>\delta w=pd(1/\rho)</math> and <math>\delta q=Tds</math>
For a reversible process: <math>\delta w=pd(1/\rho)</math> and <math>\delta q=Tds</math>
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{{NumEqn|<math>
{{NumEqn|<math>
de=Tds-pd\left(\frac{1}{\rho}\right)
de=Tds-pd\left(\frac{1}{\rho}\right)
</math>|eq-first-law-b|2}}
</math>|eq-first-law-b}}


Enthalpy is defined as: <math>h=e+p/\rho</math> and thus
Enthalpy is defined as: <math>h=e+p/\rho</math> and thus
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{{NumEqn|<math>
{{NumEqn|<math>
dh=de+pd\left(\frac{1}{\rho}\right)+\left(\frac{1}{\rho}\right)dp
dh=de+pd\left(\frac{1}{\rho}\right)+\left(\frac{1}{\rho}\right)dp
</math>|eq-dh|3}}
</math>|eq-dh}}


Eliminate <math>de</math> in {{EquationNote|eq-first-law-b}} using {{EquationNote|eq-dh}}
Eliminate <math>de</math> in {{EquationNote|eq-first-law-b}} using {{EquationNote|eq-dh}}
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{{NumEqn|<math>
{{NumEqn|<math>
Tds=dh-\cancel{pd\left(\frac{1}{\rho}\right)}-\left(\frac{1}{\rho}\right)dp+\cancel{pd\left(\frac{1}{\rho}\right)}
Tds=dh-\cancel{pd\left(\frac{1}{\rho}\right)}-\left(\frac{1}{\rho}\right)dp+\cancel{pd\left(\frac{1}{\rho}\right)}
</math>|4}}
</math>}}


{{NumEqn|<math>
{{NumEqn|<math>
ds=\frac{dh}{T}-\frac{dp}{\rho T}
ds=\frac{dh}{T}-\frac{dp}{\rho T}
</math>|5}}
</math>}}


Using <math>dh=C_p T</math> and the equation of state <math>p=\rho RT</math>, we get
Using <math>dh=C_p T</math> and the equation of state <math>p=\rho RT</math>, we get
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{{NumEqn|<math>
{{NumEqn|<math>
ds=C_p\frac{dT}{T}-R\frac{dp}{p}
ds=C_p\frac{dT}{T}-R\frac{dp}{p}
</math>|6}}
</math>}}


Integrating Eqn. \ref{eq:ds} gives
Integrating Eqn. \ref{eq:ds} gives
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{{NumEqn|<math>
{{NumEqn|<math>
s_2-s_1=\int_1^2 C_p\frac{dT}{T}-R\ln\left(\frac{p_2}{p_1}\right)
s_2-s_1=\int_1^2 C_p\frac{dT}{T}-R\ln\left(\frac{p_2}{p_1}\right)
</math>|7}}
</math>}}


For a calorically perfect gas, <math>C_p</math> is constant (not a function of temperature) and can be moved out from the integral and thus
For a calorically perfect gas, <math>C_p</math> is constant (not a function of temperature) and can be moved out from the integral and thus
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{{NumEqn|<math>
{{NumEqn|<math>
s_2-s_1=C_p\ln\left(\frac{T_2}{T_1}\right)-R\ln\left(\frac{p_2}{p_1}\right)
s_2-s_1=C_p\ln\left(\frac{T_2}{T_1}\right)-R\ln\left(\frac{p_2}{p_1}\right)
</math>|8}}
</math>}}


An alternative form of Eqn. \ref{eq:ds:c} is obtained by using <math>de=C_v dT</math> Eqn. \ref{eq:firstlaw:b}, which gives
An alternative form of Eqn. \ref{eq:ds:c} is obtained by using <math>de=C_v dT</math> Eqn. \ref{eq:firstlaw:b}, which gives
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{{NumEqn|<math>
{{NumEqn|<math>
s_2-s_1=\int_1^2 C_v\frac{dT}{T}-R\ln\left(\frac{\rho_2}{\rho_1}\right)
s_2-s_1=\int_1^2 C_v\frac{dT}{T}-R\ln\left(\frac{\rho_2}{\rho_1}\right)
</math>|9}}
</math>}}


Again, for a calorically perfect gas, we get
Again, for a calorically perfect gas, we get
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{{NumEqn|<math>
{{NumEqn|<math>
s_2-s_1=C_v\ln\left(\frac{T_2}{T_1}\right)-R\ln\left(\frac{\rho_2}{\rho_1}\right)
s_2-s_1=C_v\ln\left(\frac{T_2}{T_1}\right)-R\ln\left(\frac{\rho_2}{\rho_1}\right)
</math>|10}}
</math>}}


=== Isentropic Relations ===
=== Isentropic Relations ===